Overview of publications by the Klumperman group

accepted/in press

Hlalele, L.; Pfukwa, R.; Klumperman, B. - Simulation studies of the discrete semi-batch RAFT–mediated polymerization of styrene using a RAFT agent with relatively poor leaving group - Eur. Polym. J. 2017, 93,

Cloete, W.J.; Klumperman, B.; Cloete, T.E. - Increased functionality through surface grafting: Polymeric surfaces - Curr. Org. Chem. 2017, 21,

2017

Pfukwa, R.; Hlalele, L.; Klumperman, B., Biorelated Polymer Brushes by Surface Initiated Reversible Deactivation Radical Polymerization. In Polymers for Biomedicine, Ed. Carmen Scholz, John Wiley & Sons, Inc.: 2017; pp 487-524

Weideman, I.; Pfukwa, R.; Klumperman, B. - Phosphazene base promoted anionic polymerization of n-butyraldehyde - Eur. Polym. J. 2017, 93, 97-102

B. Klumperman in Functional Polymers by Reversible Deactivation Radical Polymerisation: Synthesis and Applications, Eds., Nikhil Singha and Jimmy W. Mays, Smithers Rapra, Shawbury, UK, 2017, Chapter 1, "Introduction into Reversible Deactivation Radical Polymerization"

2016

Reader, P.W.; Pfukwa, R.; Jokonya, S.; Arnott, G.E.; Klumperman, B. - Synthesis of α, ω-heterotelechelic PVP for bioconjugation, via a one-pot orthogonal end-group modification procedure - Polym. Chem. 2016, 7, 6450-6456

Heyns, I.M.; Pfukwa, R.; Klumperman, B. - Poly(3-methylene-2-pyrrolidone). Synthesis, characterization and evaluation of cytotoxicity - Biomacromolecules 2016, 17, 1795–1800

Gule, N.P.; Begum, N.M.; Klumperman, B. - Advances in Biofouling Mitigation: A review - Crit. Rev. Env. Sci. Technol. 2016, 46, 535-555

Giliomee, J.; Pfukwa, R.; Gule, N.; Klumperman, B. - Smart Block Copolymers of PVP and an Alkylated PVP Derivative: Synthesis, Characterization, Thermoresponsive Behaviour and Self-assembly - Polym. Chem. 2016, 7, 1138 - 1146

Rowan, S.J.; Barner-Kowollik, C.; Klumperman, B.; Gaspard, P.; Grubbs, R.B.; Hillmyer, M.A.; Hutchings, L.R.; Mahanthappa, M.K.; O’Reilly, R.K.; Ouchi, M.; Sawamoto, M.; Lodge, T.P. - Discussion on “Aperiodic Copolymers” - ACS Macro Lett. 2016, 5, 1-3

2015

Ilchev, A.; Pfukwa, R.; Hlalele, L.; Smit, M.; Klumperman, B. - Improved Control Through a Semi-Batch Process in RAFT-Mediated Polymerization Utilizing Relatively Poor Leaving Groups - Polym. Chem. 2015, 6, 7945-7948

Vermonden, T.; Klumperman, B. - The past, present and future of hydrogels - Eur. Polym. J. 2015, 72, 341-343

van Wijk, J.; Salari, J.W.O.; Meuldijk, J.; Klumperman, B. - Determination of the shell growth direction during the formation of silica microcapsules by confocal fluorescence microscopy - J. Mater. Chem. B 2015, 3, 7745 - 7751

Swanepoel, A.; du Preez, I.; Mahlangu, T.; Chetty, A. ; Klumperman, B. - Development of bioconjugated dye-doped poly(styrene-co-maleimide) nanoparticles as a new bioprobe - J. Mater. Chem. B 2015, 3, 2635-2640

2014

van Wijk, J.; Heunis, T.; Harmzen, E.; Dicks, L.M.T.; Meuldijk, J.; Klumperman, B. - Compartmentalization of bacteria in microcapsules - Chem. Commun. 2014, 50, 15427 - 15430

Klumperman, B. - The rationale behind sequence-controlled maleimide copolymers -ACS Symp. Ser. 2014, 1170, 213-221

Salari, J.W.O. ; Mutsaers, G.; Meuldijk, J.; Klumperman, B. - Deformation of the water/oil interface during the adsorption of sterically stabilized particles - Langmuir 2014, 30, 7327-7333

van Wijk, J.; van Deventer, N.; Harmzen, E.; Meuldijk, J.; Klumperman, B. - Formation of hybrid Poly(styrene-co-maleic anhydride) – Silica microcapsules - J. Mater. Chem. B 2014, 2, 4826-4835

Hadasha, W.; Klumperman, B. - Atom Transfer Radical Polymerization (ATRP) as a Powerful Tool in the Synthesis of Molecular Brushes - Polym. Int. 2014, 63, 824-834

2013

Cronje, L.; Warren, R.; Klumperman, B. - pH-Dependent adhesion of mycobacteria to surface-modified polymer nanofibers - J. Mater, Chem. B 2013, 1, 6608-6618

Cronje, L.; Klumperman, B. - Modified electrospun polymer nanofibers as affinity membranes: The effect of pre-spinning modification versus post-spinning modification - Eur. Polym. J. 2013, 49, 3814-3824

Colquhoun, H.; Klumperman, B. - Self-healing polymers - Polym. Chem. 2013, 4, 4832-4833

Pfukwa, R.; Kouwer, P.H.J.; Rowan, A.E.; Klumperman, B. - Templated hierarchical self-assembly of poly(p-aryltriazole) foldamers - Angew. Chem., Int. Ed. 2013, 52, 11040-11044

Pepels, M.; Filot, I,; Klumperman, B.; Goossens, H. - Self-healing systems based on disulfide-thiol exchange reactions - Polym. Chem. 2013, 4, 4955-4965

Shi, Y.; van den Dungen, E.; Klumperman, B.; van Nostrum, C.; Hennink, W. - RAFT synthesis of a micelle-forming thermosensitive diblock copolymer based on N-(2-hydroxy propyl) methacrylamide backbone - ACS Macro Lett. 2013, 2, 403-408

van Wijk, J.; Salari, J.W.O.; Zaquen, N.; Meuldijk, J.; Klumperman, B. - Poly(methyl methacrylate)-silica microcapsules by templating Pickering emulsion droplets - J. Mater. Chem. B 2013, 1, 2394-2406

Cloete, W.; Verwey, L.; Klumperman, B. - Permanently antimicrobial waterborne coatings based on the dual role of modified poly(styrene-co-maleic anhydride) - Eur. Polym. J. 2013, 49, 1080-1088

Gule, N.P.; de Kwaadsteniet, M.; Cloete, T.E.; Klumperman, B. - Furanone-containing poly(vinyl alcohol) nanofibers for cell-adhesion inhibition - Water Res. 2013, 47, 1049-1059

2012

Bailly, N.; Thomas, M. ; Klumperman, B. - Poly(N-vinylpyrrolidone)-block-poly(vinyl acetate) as a drug delivery vehicle for hydrophobic drugs - Biomacromolecules 2012, 13, 4109-4117

Gule, N.P.; Bshena, O.; de Kwaadsteniet, M.; Cloete, T.E.; Klumperman, B. - Immobilized furanone derivatives as inhibitors for adhesion of bacteria on modified poly(styrene-co-maleic anhydride) - Biomacromolecules 2012, 13, 3138–3150

Bailly, N.; Pound-Lana, G.; Klumperman, B. - Synthesis, characterization and self-assembly of poly(N-vinylpyrrolidone)-b-poly(vinyl acetate) - Aust. J. Chem. 2012, 65, 1124-1131

Jacobs, J.; Pound-Lana, G.; Klumperman, B. - Poly(N-vinylpyrrolidone-b-(γ-benzyl-L-glutamate)) – Synthesis and self-assembly into pH-sensitive micelles - Polym. Chem. 2012, 3, 2551 - 2560

Gule, N.P.; de Kwaadsteniet, M.; Cloete, T.E.; Klumperman, B. - Electrospun Poly(vinyl alcohol) Nanofibres with Biocidal Additives for Application in Filter Media, 1–Properties Affecting Fibre Morphology and Characterisation - Macromol. Mater. Eng. 2012, 279, 609-617

Gule, N.P.; de Kwaadsteniet, M.; Cloete, T.E.; Klumperman, B. - Electrospun Poly(vinyl alcohol) Nanofibres with Biocidal Additives for Application in Filter Media, 2–Antimicrobial Activity, Regeneration, Leaching and Water Stability - Macromol. Mater. Eng. 2012, 279, 618-626

Fantoni, R.; Salari, J.W.O.; Klumperman, B. - Structure of colloidosomes with tunable particle density: Theory vs. experiment - Phys. Rev. E 2012, 85, 061404

Klumperman, B. (2012) Controlled Composition: Statistical, Gradient, and Alternating Copolymers. In: Matyjaszewski K and Möller M (eds.) Polymer Science: A Comprehensive Reference, Vol 6, pp. 433–453. Amsterdam: Elsevier BV.

Maithufi, N.M.; Joubert, D.J.; Klumperman, B. - Synthesis and evaluation of comb-type copolymers prepared via atom transfer radical polymerization as possible cold flow improvers in GTL diesel fuels - J. Appl. Polym. Sci. 2012, 124, 2766-2776

Hlalele, L.; Klumperman, B. - Terminal Monomer Units in Dormant and Active Copolymer Chains - ACS Symp. Ser. 2012, 1100, 47-58

2011

Fleet, R.; van den Dungen, E.T.A.; Klumperman, B. – Novel glycopolymer brushes via ATRP: 1. Synthesis and characterization – Macromol. Chem. Phys. 2011, 212, 2191-2208

Fleet, R.; van den Dungen, E.T.A.; Klumperman, B. – Novel glycopolymer brushes via ATRP: 2. Thermal and mechanical properties – Macromol. Chem. Phys. 2011, 212, 2209-2216

Bshena, O.; Heunis, T.D.J.; Dicks, L.M.T.; Klumperman, B. - Antimicrobial fibres: Therapeutic possibilities and recent advances – Future Med. Chem. 2011, 3, 1821-1847

Hadasha, W.; Mothunya, M.; Akeroyd, N.; Klumperman, B. – Synthesis and Self-Assembly of Amphiphilic Hetero-Arm Molecular Brushes – Aust. J. Chem. 2011, 64, 1100-1105

Hlalele, L.; Klumperman, B. – In situ NMR and Modelling Studies of Nitroxide Mediated Copolymerization of Styrene and n-Butyl Acrylate – Macromolecules 2011, 44, 6683-6690

Hlalele, L.; Klumperman, B. – In situ 1H NMR studies of high temperature nitroxide-mediated polymerization of n-butyl acrylate – Macromolecules 2011, 44, 7100-7108

Hlalele, L.; Klumperman, B. – Reversible nitroxide-trapping of the mid-chain radical in n-butyl acrylate polymerization – Macromolecules 2011, 44, 5554-5557

Salari, J.W.O.; Jemwa, G.T.; Wyss, H.M.; Klumperman, B. – Reconstruction of the 3D structure of colloidosomes from a single SEM image – Soft Matter 2011, 7, 2033 - 2041

Akeroyd, N.; Klumperman, B. – The combination of living radical polymerization and click chemistry for the synthesis of advanced macromolecular architectures – Eur. Polym. J. 2011, 47, 1207-1231

Kyrylyuk, A.V.; Hermant, M.C.; Schilling, T.; Klumperman, B.; Koning, C.E.; van der Schoot, P. – Controlling electrical percolation in multi-component carbon nanotube dispersions – Nature Nanotech. 2011, 6, 364-369

Cloete, W.J.; Adriaanse, C.; Swart, P.; Klumperman, B. – Facile immobilization of enzymes on electrospun poly(styrene-alt-maleic anhydride) nanofibres – Polym. Chem. 2011, 2, 1479-1481

Fleet, R.; van den Dungen, E.T.A.; Klumperman, B. – Synthesis of novel glycopolymer brushes via a combination of RAFT mediated polymerization and ATRP – South African Journal of Science 2011, 107, #424

Salari, J.W.O.; Leermakers, F.A.M.; Klumperman, B. – Pickering emulsions, wetting and colloidal stability: a Self Consistent Field theory – Langmuir 2011, 27, 6574-6583

Maithufi, N.M.; Joubert, D.J.; Klumperman, B. – Application of gemini surfactants as diesel fuel wax dispersants – Energy Fuels 2011, 25, 162–171

Heunis, T.D.J.; Bshena, O.; Klumperman, B.; Dicks, L.M.T. – Release of bacteriocins from nanofibers prepared with combinations of poly(D,L-lactide) (PDLLA) and poly(ethylene oxide) (PEO) – Int. J. Mol. Sci. 2011, 12, 2158-2173

Canadell, J.; Goossens, H.; Klumperman, B. – Self-healing materials based on disulfide links – Macromolecules 2011, 44, 2536–2541

2010

Van den Dungen,E.T.A.; Loos, B.; Klumperman, B. – Use of a latent fluorophore for visualization of the rupture of capsules in self-healing coatings – Macromol. Rapid Commun. 2010, 31, 625-628

H. Matahwa, E.T.A. van den Dungen, J.B. McLeary, B. Klumperman
Title: Block, graft, star and gradient copolymer particles.
Book: Advanced polymer nanoparticles: synthesis and surface modifications
Editor: V. Mittal Publisher: Taylor & Francis Group, LLC., 2010, pp 97-131

Hermant, M.C.; van der Schoot, P.P.A.M., Klumperman, B.; Koning, C.E. – Probing the co-operative nature of the conductive components in polystyrene/poly(3,4-ethylene dioxythuiphene):poly(styrene sulfonate) – single-walled carbon nanotube composites – ACSNano 2010, 4, 2242–2248

Klumperman, B. – Mechanistic considerations on styrene – maleic anhydride copolymerization reactions – Polym. Chem. 2010, 1, 558-562

Klumperman, B.; van den Dungen, E.T.A.; Heuts, J.P.A.; Monteiro M.J. – RAFT-mediated polymerization – a story of incompatible data? – Macromol. Rapid Commun. 2010, 31, 1846-1862

Salari, J.W.O.; van Heck, J.; Klumperman, B. – Steric stabilization of Pickering emulsions for the efficient synthesis of polymeric microcapsules – Langmuir 2010, 26, 14929–14936

van den Dungen, E.T.A.; Klumperman, B. – Synthesis of liquid-filled nanocapsules via the miniemulsion technique – J. Polym. Sci., Polym. Chem. 2010, 48, 5215-5230

2009

Hermant, M.C.; Klumperman, B.; Kyrylyuk, A.V.; van der Schoot, P.; Koning, C.E. – Lowering the percolation threshold of single-walled carbon nanotubes using polystyrene/poly(3,4-ethylenedioxythiophene) : poly(styrene sulfonate) blends – Soft Matter 2009, 5, 878 - 885

Hermant, M.C.; Verhulst, M.; Kyrylyuk, A.V.; Klumperman, B.;  Koning, C.E. – The incorporation of single-walled carbon nanotubes into polymerized high internal phase emulsions to create conductive foams with a low percolation threshold – Compos. Sci. Technol. 2009, 69, 656-662

Klumperman, B.; Pound-Lana, G. - Reversible Addition Fragmentation Chain Transfer (RAFT) Mediated Polymerization of N-Vinylpyrrolidone: RAFT agent design – Controlled/Living Radical Polymerization: Progress in RAFT, NMP & OMRP; Ed. K. Matyjaszewski - ACS Symposium Series - 2009, 1024, 167-180

Akeroyd, N.; Pfukwa, R.; Klumperman, B. – A triazole-based leaving group for RAFT-mediated polymerization, synthesized via the Cu-mediated Huisgen 1,3-dipolar cycloaddition reaction – Macromolecules 2009, 42, 3014-3018

Hermant, M.C.; Klumperman, B.;  Koning, C.E. – Conductive Pickering - Poly(high internal phase emulsion) Composite Foams prepared with low loadings of Single-Walled Carbon Nanotubes – Chem. Commun. 2009, 19, 2738-2740

Ahmad, N.M.; Charleux, B.; Farcet, C.; Ferguson, C.J.; Gaynor, S.G.; Hawkett, B.S.; Heatley, F.; Klumperman, B.; Konkolewicz, D.; Lovell, P.A.; Matyjaszewski, K.; Venkatesh, R. – Chain transfer to polymer and branching in controlled radical polymerizations of n-butyl acrylate – Macromol. Rapid Commun.­ 2009, 30, 2002–2021

Hermant, M.C.; Smeets, N.M.B.; van Hal,R.C.F. Meuldijk, J.; Heuts, H.P.A.; Klumperman, B.; van Herk,A.M.; Koning, C.E. – Influence of the molecular weight distribution on the percolation threshold of carbon nanotube – polystyrene composites – e-Polymers 2009, 022

2008

van den Dungen, E.T.A.; Matahwa, H.; McLeary, J.B.; Sanderson, R.D.; Klumperman, B. – Initialization behavior for high target molecular weight polymers using various dithiobenzoates – J. Polym. Sci., Polym. Chem. 2008, 46, 2500-2509

Pound, G.; McKenzie, J.M.; Lange, R.F.M.; Klumperman, B. –  Polymer-protein conjugates from ω-aldehyde endfunctional poly(N-vinylpyrrolidone) synthesized via xanthate-mediated living radical polymerization – Chem. Commun. 2008, 18, 3193-3195

Pound, G.; Eksteen, Z.; Pfukwa, R.; McKenzie, J.M.; Lange, R.F.M.; Klumperman, B. – Unexpected reactions associated with the xanthate-mediated polymerization of N-vinylpyrrolidone – J. Polym. Sci. Part A: Polym. Chem. 2008, 46, 6575-6593

2007

Klumperman, B. – Living radical polymerization – Encyclopedia of Polymer Science and Technology, Concise, 3rd Ed., John Wiley & Sons, 2007, ISBN: 978-0-470-04610-4

Klumperman, B.- Statistical, alternating and gradient copolymers - Macromolecular Engineering: Precise Synthesis, Materials Properties, Applications,
K. Matyjaszewski (Editor), Y. Gnanou (Editor), L. Leibler (Editor), John Wiley & Sons, 2007, ISBN: 978-3-527-31446-1

Božović-Vukić, J.; Tello Mañon, H.; Meuldijk, J.; Koning, C.; Klumperman, B. – SAN-b-P4VP block copolymer synthesis by chain extension from RAFT-functional poly(4-vinyl pyridine) in solution and in emulsion – Macromolecules 2007, 40, 7132-7139

Pound, G.; Aguesse, F.; McLeary, J.B.; Lange, R.F.M.; Klumperman, B. – Xanthate-Mediated Copolymerization of Vinyl Monomers for Amphiphilic and Double-Hydrophilic Block Copolymers with Poly(ethylene glycol) -  Macromolecules 2007, 40, 8861-8871

Klumperman, B.; McLeary, J.B.; van den Dungen, E.T.A.; Pound, G. – NMR Spectroscopy in the Optimization and Evaluation of RAFT Agents – Macromol. Symp. 2007, 248, 141-149

Geelen, P.; Klumperman, B. - Intermediate Radical Termination in RAFT mediated polymerization – Identification of termination products – Macromolecules 2007, 40, 3914-3920

2006

McLeary, J.B.; Klumperman, B. – RAFT mediated polymerisation in heterogeneous media – Soft Matter 2006, 2, 45-53

Klumperman, B.; McLeary, J.B.; Soer, W.-J.; Božović, J.S.;  - RAFT-mediated Copolymerizations – The Challenge of Random Copolymer Blocks - Controlled Radical Polymerization; Ed. K. Matyjaszewski - ACS Symposium Series 2006, 944, 501-513

Vukić, J.; Hoeppener, S.; Kozodaev, D.; Kišin, S.; Klumperman, B.; Koning, C.; Schubert, U.S.; de With, G. – Investigation on the nanoscopic and macroscopic scale of the interaction between copper and the model copolymers SAN and SMAh – Chem. Phys. Chem. 2006, 7, 1912-1916

Klumperman, B. – Styrene/maleic anhydride macro-RAFT-mediated encapsulation – Macromol. Chem. Phys. 2006, 207, 861-863

McLeary, J.B.; Tonge, M.P.; Klumperman, B. – A mechanistic interpretation of initialization processes in RAFT-mediated polymerization – Macromol. Rapid. Commun. 2006, 27, 1233-1240

Pound, G.; McLeary, J.B.; McKenzie, J.; Sanderson, R.D.; Klumperman, B. – Probing the efficiency of RAFT agents with in situ NMR spectroscopy – Macromolecules 2006, 39, 7796-7797

van den Dungen, E.T.A.; Rinquest, J.; Pretorius, N.O.; McKenzie, J.M.; McLeary, J.B.; Sanderson, R.D.; Klumperman, B. -  Investigation into the initialization behavior of RAFT mediated styrene – maleic anhydride copolymerizations – Aust. J. Chem. 2006, 59, 742-748

Bussels, R.; Bergman-Göttgens, C.; Klumperman, B.; Meuldijk, J.; Koning, C. - Triblock Copolymer Synthesis via Controlled Radical Polymerization in Solution using S-tert-Alkyl-N,N-alkoxycarbonylalkyldithiocarbamate RAFT Agents – J. Polym. Sci., Polym. Chem. Ed. 2006, 44, 6419-6434

Barner-Kowollik, C; Buback, M; Charleux, B.; Coote, M.L.; Drache, M.; Fukuda, T.; Goto, A.; Klumperman, B.; Lowe, A.B.; McLeary, J.B.;Moad, G.; Monteiro, M.J.; Sanderson, R.D., Tonge, M.P.; Vana, P. – Mechanism and kinetics of dithiobenzoate-mediated RAFT polymerization, 1. The curent situation – J. Polym. Sci. Part A: Polym. Chem. 2006, 44, 5809-5831

Soer, W.J., Ming, W., Klumperman, B., Koning, C., van Benthem, R. –Surfactant-free artificial latexes from modified styrene maleic anhydride (SMA) copolymers – Polymer 2006, 47, 7621-7627

2005

Lima, V.; Jiang, X.; Brokken-Zijp, J.; Schoenmakers, P.J.; Klumperman, B.; van der Linde, R. – Synthesis and characterization of telechelic polymethacrylates via RAFT polymerization – J. Polym. Sci., Polym. Chem. Ed. 2005, 42, 959-973

Venkatesh, R.; Vergouwen, F.; Klumperman, B. – Atom transfer radical copolymerization of α-olefins with methyl acrylate: determination of activation rate parameters – Macromol. Chem. Phys. 2005, 206, 547-552

McLeary, J.B.; Hermant, M.C.; Matahwa, H.; Klumperman, B.; Sanderson, R.D. – Anomalies in RAFT mediated miniemulsion polymerization – Polymer Preprints 2005, 46(2), 140-141

Klumperman, B.; McLeary, J. B.; Božović, J. – RAFT mediated copolymerizations - the challenge of random copolymer blocks. – Polymer Preprints 2005, 46(2), 378-379

Donkers, E.H.D; Willemse, R.X.E.; Klumperman, B. – Chain end modification of living anionic polybutadiene with diphenylethylenes and styrenes – J.Polym. Sci., Polym. Chem. Ed. 2005, 43(12), 2536-2545

Staal, M.; Weber, M.; Koning, C.E.; Klumperman, B. – Functional group distribution over the molar mass distribution of SAN-MAh compatibilizers for PA/ABS blends – J.Polym. Sci., Polym. Chem. Ed. 2005, 43(12), 2536-2545

McLeary, J.B.; Calitz, F.M.; McKenzie, J.M.; Tonge, M.P.; Sanderson, R.D.; Klumperman, B. – A 1H NMR investigation of reversible addition fragmentation chain transfer (RAFT) polymerization kinetics and mechanism; initialization with different initiating and leaving groups – Macromolecules 2005, 38, 3151-3161

van Zyl, A.J.P.; Bosch, R.F.P.; McLeary, J.B.; Klumperman, B. – Synthesis of liquid-filled polymeric nanocapsules through the use of living polymerization techniques – Polymer 2005, 46, 3607-3615

2004

Venkatesh, R.; Staal, B.B.P.;  Klumperman, B.; Monteiro, M.J. –Characterization of 3- and 4-Arm Stars from Reactions of Poly(butyl acrylate) RAFT and ATRP Precursors – Macromolecules 2004, 37(21), 7906-7917

Venkatesh, R.; Yajjou, L.; Koning, C.E.; Klumperman, B. – Novel Brush Copolymers via Controlled Radical Polymerization – Macromol. Chem. Phys. 2004, 205(16), 2162-2168

Kelemen, P.; Klumperman, B. – Determination of the free radical concentration ratio in the copolymerization of methyl acrylate and styrene. Application of radical trapping and 15N NMR spectroscopy – Macromolecules 2004, 37(25), 9338-9344

Venkatesh, R.; Klumperman, B. – Olefin copolymerization via controlled radical polymerization: copolymerization of methyl methacrylate and 1-octene – Macromolecules 2004, 37, 1226-1233

Venkatesh, R.; Harrison, S.; Haddleton, D.M.; Klumperman, B. – Olefin copolymerization via controlled radical polymerization: copolymerization of acrylate and 1-octene – Macromolecules 2004, 37(12), 4406-4416

van Zyl, A.; Sanderson, R.D.; de Wet-Roos, D.; Klumperman, B. – The Role of Surfactant in Controlling Particle Size and Stability in the Miniemulsion Polymerization of Polymeric Nanocapsules – Eur. Polym. J. 2004, 40, 2717-2725

Venkatesh, R.; Staal, B.; Klumperman, B – Olefin copolymerization via reversible addition-fragmentation chain transfer – Chem. Comm. 200413, 1554-1555

Venkatesh, R.; Vergouwen, F.; Klumperman, B. – Copolymerization of allyl butyl ether (ABE) with acrylates via controlled radical polymerization – J. Polym. Sci., Polym. Chem. Ed. 2004, 42(13), 3271-3284

McLeary, J.B.; McKenzie, J. M.; Tonge, M. P.; Sanderson, R. D.; Klumperman, B. – Initialisation in RAFT-mediated polymerisation of methyl acrylate – Chem. Comm.2004, 17, 1950-1951

McLeary, J.B.; Calitz, F.M.; McKenzie, J.M.; Tonge, M. P.; Sanderson, R. D.; Klumperman, B. – Beyond inhibition: A 1H NMR investigation of the early kinetics of RAFT mediated polymerization with the same initiating and leaving groups.  – Macromolecules 2004, 37, 2383-2394

Beyers, C.P.; Boelens, H.F.M.; Klumperman, B.; Westerhuis, J.A. – In-line reaction monitoring of a methyl methacrylate and N,N-dimethylacrylamide copolymerization reaction using near-infrared spectroscopy – Appl. Spectrosc. 2004, 58(7), 863-869

Klumperman, B. – Living radical polymerization – Encyclopedia of Polymer Science and Technology, 3rd Ed., John Wiley & Sons, 2004, ISBN: 978-0-471-27507-7

McLeary, J.B.; Tonge, M.P.; de Wet-Roos, D.; Sanderson, R.D.; Klumperman, B. – Controlled radical reversible addition-fragmentation chain transfer (RAFT) polymerization in high surfactant concentration ionic miniemulsions – J. Polym. Sci., Polym. Chem. Ed. 2004, 42, 960-974

2003

Singha, N.K.; Rimmer, S.; Klumperman, B. – Mass spectrometry of Poly(methyl methacrylate) (PMMA) prepared by Atom Transfer  Radical Polymerization (ATRP) – Eur. Polym. J. 2004, 40, 159-163

van Zyl, A.; Sanderson, R.D.; de Wet-Roos, D.; Klumperman, B. – Core/Shell Particles Containing Liquid Cores: Morphology Prediction, Synthesis and Characterization – Macromolecules 2003, 36, 8621-8629

Calitz, F. M.; McLeary, J. B.; McKenzie, J. M.; Tonge, M. P.; Klumperman, B.; Sanderson, R. D.  Evidence for Termination of Intermediate Radical Species in RAFT-Mediated Polymerization – Macromolecules 2003, 36, 9687-9690

Beuermann, S.; Buback, M.; Davis, T.; Hutchinson, R.; Klumperman, B.; Kajuewara, A.; Lacik, I.; Russell, G.; Abe, A.; Ando, I.; Baron, M.; Berek, D.; Chan, H.; Chen, J.-Y. F.; Costa, G.; Economyu, J.; Fuller, G.; Gilbert, R. G.; Hess, M.; Hvilsted, S.; Horic, K.; Jin, J.-I.; Jones, R. G.; Khokhlov, A. R.; Kratochvil, P.; Kubisa, P.; Laun, H. M.; Pascault, J.-P.; Penczek, S.; Perena, J. M.; Reichmanis, E.; Sanderson, R. D.; Seppaelae, J. V.; Gomes, A. de Souza; Stepto, R. F. T.; Tabak, D.; Tenhu, H.; Vairon, J.-P.; Vohlidal, J.; Wang, F.; Work, W. J. – Critically evaluated propagation rate coefficients in free-radical polymerizations: Part III. methacrylates with cyclic ester groups (IUPAC Technical Report) – Pure and Applied Chemistry 2003, 75, 1091-1096

Willemse, R.X.E.; Staal, B.B.P.; van Herk, A.M.; Pierik, S.C.J.; Klumperman, B. – Application of Matrix-Assisted Laser Desorption Ionization Time-of-Flight Mass Spectrometry in Pulsed Laser Polymerization. Chain-Length-Dependent Propagation Rate Coefficients at High Molecular Weight: An Artifact Caused by Band Broadening in Size Exclusion Chromatography? – Macromolecules 2003, 36(26), 9797-9803

Chambard, G.; Klumperman, B.; Brinkhuis, R.H.G. – Peculiarities in atom transfer radical copolymerization – Advances in Controlled/Living Radical Polymerization; Ed. K. Matyjaszewski - ACS Symposium Series 2003, 854, 180-192

Karanam, S.; Goossens, H.; Klumperman, B.; Lemstra, P. – Controlled synthesis and characterization of high molecular weight methyl methacrylate/tert-butyl methacrylate diblock copolymers via ATRP – Macromolecules 2003, 36, 8304-8311

Karanam, S.; Goossens, H.; Klumperman, B.; Lemstra, P. – “Controlled” synthesis and characterization of model methyl methacrylate/tert-butyl methacrylate triblock copolymers via ATRP – Macromolecules 2003, 36, 3051-3060

Kelemen, P; Klumperman, B. – Detection of free radicals by  radical trapping and  15N NMR spectroscopy in  copolymerization of methylacrylate and styrene – Polymer Preprints 2003, 44(1), 1049-1050

Venkatesh, R.; Klumperman, B. – Olefin copolymerization using atom transfer radical polymerization (ATRP) – Polymer Preprints 2003, 44(1), 798-799

Venkatesh, R.; Harrison, S.; Klumperman, B.; Haddleton, D.M. – Olefin copolymerization using atom transfer radical polymerization (ATRP) – Determination of reactivity ratios – Polymer Preprints 2003, 44(1), 796-797

van Zyl, A.J.P.; de Wet-Roos, D.; Sanderson, R.D.; Klumperman, B. – Synthesis of liquid-filled polymeric nanocapsules: Morphology analysis, role of surfactant and the use of living polymerization techniques – Polymer Preprints 2003, 44(1), 777-778

McLeary, J.B.; Tonge, M.; Sanderson, R.D.; Klumperman, B. - Reversible addition fragmentation polymerization in heterogeneous media – Polymer Preprints 2003, 44(1), 781-782

Lima, V.; Brokken-Zijp, J.; Klumperman, B.; van Benthem-van Duuren, G.; van der Linde, R. – Synthesis and characterization of telechelic polymers prepared by RAFT – Polymer Preprints 2003, 44(1), 812-813

Kelemen, P.; Lugtenburg, J.; Klumperman, B. – 15N NMR spectroscopy of labeled alkoxyamines. 15N labeled model compounds for nitroxide-trapping studies in free radical (co)polymerization. – J. Org. Chem. 2003, 68, 7322-7328

Graef, S.M.; van Zyl, A.J.P.; Sanderson, R. D.; Klumperman, B.; Pasch, H. – The use of gradient, critical and 2-dimensional chromatography in the analysis of styrene- and methyl methacrylate-grafted epoxidized natural rubber – J. Appl. Polym. Sci. 2003, 88, 2530-2538

van Zyl, A.J.P.; Graef, S.M.; Sanderson, R. D.; Klumperman, B.; Pasch, H. – Monitoring the grafting of epoxidized natural rubber by size-exclusion chromatography coupled to FTIR spectroscopy – J. Appl. Polym. Sci. 2003, 88, 2539-2549

2002

Chambard, G.; Klumperman, B.  The effect of initiation on atom transfer radical copolymerization – Polymer Preprints 2002, 43(2), 9-10

Snijder, A.; Klumperman, B.; van der Linde, R. – End-group modification of poly(butyl acrylate) prepared by atom transfer radical polymerization: mechanistic study using gradient polymer elution chromatography – J. Polym. Sci., Part A: Polym. Chem. 2002, 40(14), 2350-2359

Zhang, H.; Klumperman, B.; van der Linde, R. – Synthesis of Anthracene End-capped Poly(methyl methacrylate)s via Atom Transfer Radical Polymerization and Its Kinetic Analyses – Macromolecules 2002, 35, 2261-2267

Snijder, A.; Klumperman, B.; van der Linde, R. – Kinetics of heterogeneous ATRP of methyl methacrylate – Macromolecules 2002, 35, 4785-4790

Chambard, G.; Klumperman, B.; German, A.L.  – Experimental determination of the rate constant of deactivation of poly(styrene) and poly(butyl acrylate) radicals in atom transfer radical polymerization – Macromolecules 2002, 35, 3420-3425

Philipsen, H.J.A.; Klumperman, B.; Leermakers, F.A.M.; Wubbe, F.P.C.; German, A.L. – Molar mass effects in reversed-phase gradient polymer-elution chromatography of oligomers – Chromatographia 2002, 55, 533-540

Leermakers, F.A.M.; Philipsen, H.J.A.; Klumperman, B. – Molecular modeling of chain end effects in separating oligomers by reversed phase gradient polymer elution chromatography; adsorption transition as revealed by a self-consistent-field theory for polymer adsorption – Chromatogr. 2002, 959, 37-47

2001

Schellekens, M.A.J.; de Wit, F.; Klumperman, B. – Effect of copper counterion on the activation rate parameter in atom transfer radical polymerization – Macromolecules 2001, 34, 7961-7966

Schellekens, M.A.J.; Klumperman, B.; van der Linde, R. – Synthesis of poly(ethylene-co­-butylene)-poly(methyl methacrylate) block copolymers by atom transfer radical polymerization: determination of the macroinitiator conversion – Macromol. Chem. Phys. 2001, 202, 1595-1601

de Vries, A.; Klumperman, B.; de Wet-Roos, D.; Sanderson, R.D. – The effect of monosaccharide reducing sugars on the atom transfer radical polymerization of butyl methacrylate – Macromol. Chem. Phys. 2001, 202, 1645-1648

Zhang, H.; Klumperman, B.; Ming, W.; van der Linde, R.; Fischer, H. – Effect of Cu(II) on the kinetics of the homogeneous atom transfer radical polymerization of methyl methacrylate – Macromolecules 2001, 34, 6169-6173

2000

Schellekens, M.A.J.; Klumperman, B. – Synthesis of Polyolefin Block and Graft Copolymers – J. Macromol. Sci., Rev. Macromol. Chem. Phys. 2000, C40, 167-192

Beuermann, S.; Buback, M.; Davis, T.P.; Gilbert, R.G.; Hutchinson, R.A.; Kajiwara, A.; Klumperman, B.; Russell, G.T. – Critically evaluated rate coefficients for free-radical polymerization, 3. Propagation rate coefficients for alkyl methacrylates – Macromol. Chem. Phys. 2000, 201, 1355-1364

Chambard, G.; Klumperman, B.; German, A.L. – Effect of solvent on the activation rate parameters for polystyrene and poly(butyl acrylate) macroinitiators in atom transfer radical polymerization – Macromolecules 2000, 33, 4417-4421

de Brouwer, J.A.M.; Schellekens, M.A.J.; Klumperman, B.; Monteiro, M.J. – Controlled radical copolymerisation of styrene and maleic anhydride and the synthesis of novel polyolefin-based block copolymers by reversible addition-fragmentation chain-transfer (RAFT) polymerization – J. Polym. Sci., Chem. Ed. 2000, 38, 3596-3603

Chambard, G.; Klumperman, B. – Atom transfer radical (co)polymerization of styrene and butyl acrylate – Controlled Radical Polymerization; Ed. K. Matyjaszewski - ACS Symposium Series 2000, 768, 197-210

Singha, N.K.; Klumperman, B. – Atom transfer radical polymerization of methyl methacrylate (MMA) using CuSCN as catalyst – Macromol. Rapid Commun. 2000, 21, 1116-1120

Marks, M.J.; Munjal, S.; Namhata, S.; Scott, D.C.; de Letter, J.A.; Klumperman, B. – Randomly branched bosphenol A polycarbonates. 1. Molecular weight distribution modeling, interfacial synthesis, and characterization – J. Polym. Sci., Polym. Chem. Ed. 2000, 38, 560-570

Philipsen, H.J.A.; Claessens, H.A.; Jandera, P.; Bosman, M.; Klumperman, B. - Chromatographic behaviour of low molar mass polyesters in normal-phase high performance liquid chromatography – Chromatographia 2000, 52, 325-333

Chambard, G.; de Man, P.; Klumperman, B. – Atom transfer radical polymerization in emulsion – Macromol. Symp.2000, 150, 45-51

1999

Chambard, G.; Klumperman, B.; German, A.L. - Dependence of chemical composition of styrene/butyl acrylate copolymers on temperature and molecular weight - Polymer1999, 40, 4459-4463

Philipsen, H.J.A.; Wubbe, F.P.C.; Klumperman, B.; German, A.L. – Microstructural characterization of aromatic copolyesters made by step reactions, by gradient polymer elution chromatography – J. Appl. Polym. Sci. 1999, 72, 183-201

Aerdts, A.M.; van Herk, A.M.; Klumperman, B.; Kurja, J.; German, A.L. – Emulsion Polymerisation, Chapter 9 in “Materials Science and Technology Series, Ed. Schlüter, A.-D. - Wiley VCH, 1999, Ed. Schlüter, A.-D. - Wiley VCH, 1999, 271-317

Klumperman, B.; Chambard, G. – Recent advances in atom transfer radical copolymerization – Polym. Prepr. 1999, 40(2), 329-330

1998

Philipsen, H.J.A.; Klumperman, B.; German, A.L. – Characterization of copolymers by gradient polymer elution chromatography – Proc. Int. GPC Symp., Phoenix, 1998, 383-413

Klumperman, B.; Philipsen, H.J.A. - Gradient polymer elution chromatography as a versatile tool in polymer characterization - LC GC EuropeJanuary 1998, 18-25

Heinen, W.; Wenzel, C.B.; Rosenmöller, C.H.; Mulder, F.; Boender, G.J.; Lugtenburg, J.; de Groot, H.J.M.; van Duin, M.; Klumperman, B. – Solid state 13C NMR study of miscibility and phase separation in blends and semi-interpenetrating networks of poly(styrene-co-acrylonitrile) and poly(styrene-co­-maleic anhydride) – Macromolecules 1998, 31, 7404-7412

Bon, S.A.F.; Bergman, F.A.C.; van Es, J.J.G.S.; Klumperman, B.; German, A.L. - Nitroxide-mediated controlled radical polymerization: towards control of molar mass - Controlled Radical Polymerization; Ed. K. Matyjaszewski - ACS Symposium Series1998, 685, 236-255

Philipsen, H.J.A.; Claessens, H.A.; Bosman, M.; Klumperman, B.; German, A.L. – Normal phase gradient polymer elution chromatography of polyester resins - Chromatographia  1998, 48, 623-630

Coote, M.L.; Davis, T.P.; Klumperman, B.; Monteiro, M. - A mechanistic perspective on solvent effects in free radical copolymerization - J. M. S. - Rev. Macromol. Chem. Phys. 1998, C38, 567-593

1997

Philipsen, H.J.A.; Oestreich, M.; Klumperman, B.; German, A.L. - Characterization of low molar mass polymers by gradient polymer elution chromatography III: Behaviour of crystalline polyesters under reversed phase conditions - J. Chromatogr. - 1997, 775, 157-177.

O’Driscoll, K.F.; Monteiro, M.J.; Klumperman, B. - The effect of benzyl alcohol on pulsed laser polymerization of styrene and methylmethacrylate - J. Polym. Sci., Chem. Ed. - 1997, 35, 515-520.

de Kock, J.B.L.; Klumperman, B.; van Herk, A.M.; German, A.L. - A theoretical description of a method for model independent determination of bimolecular chain length dependent free radical termination rate coefficients - Macromolecules - 1997, 30, 6743-6753.

Philipsen, H.J.A.; Claessens, H.A.; Lind, H.; Klumperman, B.; German, A.L. - A study on the retention behaviour of low molar mass polystyrenes and polyesters in reversed phase liquid chromatography by evaluation of thermodynamic parameters - J. Chromatogr.1997, 790, 101-116

Philipsen, H.J.A.; de Cooker, M.R.; Claessens, H.A.; Klumperman, B.; German, A.L. - Characterization of low molar mass polymers by gradient polymer elution chromatography II: Solubility effects in the analysis of polyesters resins under reversed phase conditions - J. Chromatogr. - 1997, 761, 147-162.

Bon, S.A.F.; Bosveld, M.; Klumperman, B.; German, A.L. - Controlled radical polymerization in emulsion - Macromolecules - 1997, 30, 324-326.

Bon, S.A.F.; Chambard, G.; Bergman, F.A.C.; Snellen, E.H.H.; Klumperman, B.; German, A.L. – Controlled radical polymerization: control of molecular weight, composition and stereoregularity in homogeneous and heterogeneous systems – Polym. Prepr. 1997, 38(1), 748-749

1996

Manders, B.G.; Chambard, G.; Kingma, W.J.; Klumperman, B.; van Herk, A.M.; German, A.L. - Estimation of activation parameters for the propagation rate constant of styrene - J. Polym. Sci., Polym. Chem. Ed. - 1996, 34, 2473-2479.

German, A.L.; Manders, B.G., Zirkzee, H.F.; Klumperman, B.; van Herk, A.M. - Local monomer concentrations in emulsion polymerization - Macromol. Symp. - 1996, 111, 107-120.

Philipsen, H.J.A.; Klumperman, B.; van Herk, A.M.; German, A.L. - Critical rentention behaviour of polymers: a study to the influence of some practical parameters - J. Chromatogr. - 1996, 727, 13-25.

Cools, P.J.C.H.; Maesen, F.; Klumperman, B.; van Herk, A.M.; German, A.L. - Determination of the chemical composition distribution of styrene and butadiene by gradient polymer elution chromatography (GPEC) - J. Chromatogr. - 1996, 736, 125-130.

Klumperman, B.; Cools, P.; Philipsen, H.; Staal, W. - A qualitative study to the influence of molar mass on retention in gradient polymer elution chromatography - Macromol. Symp. - 1996, 110, 1-13.

Philipsen, H.J.A.; Klumperman, B.; German, A.L. - Characterization of low molar mass polymers by gradient elution chromatography I: Practical parameters and applications of the analysis of polyester resins under reversed phase conditions - J. Chromatogr. - 1996, 746, 211-224.

Klumperman, B.; Aerdts, A.M. - Copolymerization of styrene and methyl methacrylate in ternary oil-in-water microemulsions: comments on a paper by L.M. Gan et al. - Macromolecules - 1996, 29, 6679-6680.

1995

O’Driscoll, K.F.; Davis, T.P.; Klumperman, B.; Madruga, E.L. - Solvent effects in copolymerization - Macromol. Rapid Commun. - 1995, 16, 207-210.

Buback, M.; Gilbert, R.G.; Hutchinson, R.A.; Klumperman, B.; Kuchta, F.D.; Manders, B.G.; O’Driscoll, K.F.; Russell, G.T.; Schweer, J. - Critically evaluated rate coefficients for free-radical polymerzation, 1. Propagation rate coefficients for styrene - Macromol. Chem. Phys. - 1995, 196, 3267-3280.

1994

Klumperman, B.; Kraeger, I.R. - The effect of solvent on the copolymerization of styrene and acrylonitrile. Application of the bootstrap effect to the penultimate unit model - Macromolecules  - 1994, 27, 1529-1534.

Klumperman, B.; Vonk, G. - Solvent effects on the copolymerization of styrene with maleic anhydride. Determination of apparent reactivity ratios from the penultimate unit model - Eur. Polym. J. - 1994, 30, 955-960.

Sanayei, R.A.; O’Driscoll, K.; Klumperman, B. - Pulsed laser copolymerization of styrene and maleic anhydride - Macromolecules - 1994, 27, 5577-5582.

Klumperman, B.; Brown, P.G. - Interpretation of solvent effects on styrene/maleic anhydride copolymer sequence distribution and microstructure in terms of the bootstrap effect - Macromolecules - 1994, 27, 6100-6101.

1993

Klumperman, B.; O’Driscoll, K.F. - Interpreting the copolymerization of styrene with maleic anhydride and with methyl methacrylate in terms of the bootstrap model - Polymer  - 1993, 34, 1032-1037.

1991

Klumperman, B.; Smids, P.; Duin, M. van - Oligomer formation during the copolymerization of styrene and maleic anhydride - Integr. Fundam. Polym. Sci. Technol. -5, [Proc. Int. Meet. Polym. Sci. Technol., Rolduc Polym. Meet.-5] 5th 1990, (Pub. 1991) 100-103 Ed. Lemstra, P.J.; Kleintjens, L.A.L.: London, UK.